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If you mean screenshots, taken with Print Screen or a program like Fraps or Gadwin, you'll find them where ever the program put them. It will vary with the system.
If you mean the snapshots taken with the camera provided by the game, each neighborhood has a Storytelling folder. The path will be MyDocuments/EAGames/Sims2/Neighborhoods/N001 (or whatever)/Storytelling. N001, 2, and 3 are the base game hoods, N004 and up are custom hoods, the hoods that came with later EPs begin with other letters.
The pictures will be in two versions, thumbnail and snapshot, and will follow the protocol: picture type_randomalphanumericidentifyinghousehold_randomalphanumeric.jpg. If you arrange the folder by date modified, viewing icons or thumbnails, you'll be able to find your most recent ones easily.
Do not get distracted by the Storytelling folder outside the Neighborhood folder. That only holds the last shots taken and is a holdover from base game, where the albums were handled differently.
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